THE DEVELOPMENT OF WORKSHEET IN THE EXPERIMENT OF CREATING INDICATOR PAPERS

This study aimed to describe the worksheet's appearance and analyze the worksheet's validation test result based on POE (Predict, Observe, Explain). This research's objectives were to describe the development of a worksheet used in creating indicator papers from Aerva sanguinolenta plants and analyze the feasibility test result on its format. The stages of developing worksheets consist of preparation (define) the stage by analyzing research literature on indicator papers from Aerva sanguinolenta, planning stage by designing laboratory activities in worksheets, and development stage by conducting trials on worksheet products. The worksheet's feasibility was then tested. The results were validated with the average r-count value from the validators of 0.92, the average feasibility value percentage of 92%, the average r-count value from the students of 0.93, and the average feasibility value percentage of 93%. Therefore, the worksheet can be used as a learning aid for students in conducting experiments.


INTRODUCTION
Basically, chemistry consists of two aspects: chemistry as product and process (Trianto, 2010). Its conceptual scope is broad, ranging from simple to very complex levels (Sari and Hidayat, 2016). Chemistry learning should not set aside chemical processing practices since most of the concepts in Chemistry were generated from laboratory experiments. Chemistry itself belongs to experimental studies (Chang, 2005). Experimental methods could develop students' scientific thinking and process skills (Yunita, 2012).
A worksheet is one of the learning aids that helps students perform more directed learning. With the right method, a worksheet could develop students' critical thinking and active learning (Nurhidayati et al., 2017;Muna, 2017). Students' active learning can be developed through three phases: 1) the predict phase, where students predict the possible results from experiment regarding certain inclinations or patterns; 2) the observe phase, where students acquire data or information by conducting and observing experiment; and 3) the explain phase, where students compare and explain in details the predicted results and the observed results (Suhartatik et al., 2013).
A worksheet can be used in learning materials on indicators from natural materials. The indicators from natural materials belong to the concepts of acid-base that were taught at 11th grade in 2nd semester Senior High Schools. Anthocyanins are vacuolar pigments and may appear red, blue, and purple. They were contained in several fruits, vegetables and decorative plants (Lestari, 2016). Aerva Jurnal Tadris Kimiya 5, 2 (December 2020): [187][188][189][190][191][192][193][194] This is an open access article under CC-BY-SA license (https://creativecommons.org/licenses/by-sa/4.0/) The Development of Worksheet in the Chemistry Experiment Learning of Creating Natural Indicator Papers sanguinolenta plants (Aerva sanguinolenta in Latin or Sambang colok in Indonesian) contain anthocyanins and are potential to be used as natural indicators (Warsiki et al., 2013). Often, natural indicators used in laboratories are in form of liquid solution. But that form could be damaged easily and will not last long for future use, especially in Chemistry learning (Yunita, 2014). Therefore, it is necessary to develop a better alternative: a new natural indicator which will be created from Aerva sanguinolenta plants. The new natural indicator will be developed in form of a paper sheet for longer storability purpose. In facilitating the creation of the new natural indicator, a worksheet that guides students in conducting active and independent learning will be developed.

RESEARCH METHOD
The method used in this research was Design-Based Research (DBR) (Reevers, 2006). It refers to the 4D Development model (Define, Design, Develop and Disseminate). However, only the first three phases were conducted in this research.
The tools used in this research were 200 ml beaker, analytical balance, mortar and pestle, spatula, 100 ml measuring cup, drop pipette, glass funnel, water bath, oven, baking sheet, Whatman TM no. 40 filter papers, 70 gsm HVS papers, and coarse filter papers. The materials used in this research were Aerva sanguinolenta plants, methanol, ethanol, and water. The feasibility of the research product (the worksheet) was tested by experts (media and chemistry lectures) and limited test by students until it was considered valid. The instrument of the feasibility test was a validation questionnaire. The quantitative data analysis on the validity result consists of two phases,that is analyzing data in the Likert scale questionnaire and processing data in the Guttman scale questionnaire (Arikunto, 2010).
Next, the results of the feasibility test were analyzed by comparing the values of r-count and the value of r-critical (0.30). If a value of r-count is bigger than 0.30, then the related criterion item is considered valid. Conversely, if a value of r-count is smaller than 0.30, then the related criterion item is considered invalid (Arikunto, 2010). The processing of the data from the Guttman scale questionnaire which was acquired from limited respondents was performed by adding all values in the columns and converting them into percentage format (Sudjana, 2009).

RESULT AND DISCUSSION
The development of indicator papers from Aerva sanguinolenta plants consists of analyzing anthocyanins that contained in the extract of the plants, creating indicator papers from the plants and testing pH scale on the indicator papers. The experiment that the worksheet was used consists of creating indicator papers from Aerva sanguinolenta plants which were shaped like litmus paper for testing acidity and basicity levels. By following Lestari (2016) research, shows that paper indicators created from natural materials were more practical in usage and long-lasting compared to liquid natural indicators. Aerva sanguinolenta plants were selected because they are easy to find. Also, the plants contain anthocyanin pigments that can be used for creating natural indicators (Warsiki et al., 2013). The next step was to draft the design of the worksheet and tested in a laboratory experiment. The worksheet for creating pH indicators from natural materials was structured according to predict, observe and explain phases (Sudiadnyani et al., 2013). The appearance of a POE based worksheet on making indicator paper experiment from Aerva sanguinolenta plant can be seen in Figure 1.
The discourse contains content regarding indicators of acid-base in the form of litmus paper, Aerva sanguinolenta as a natural indicator, and procedures for making indicator paper from Aerva sanguinolenta that resemble litmus paper.
The Development of Worksheet in the Chemistry Experiment Learning of Creating Natural Indicator Papers  Figure 1 and 2 are included in the predict phase in the worksheet. In the predict phase, assumptions on the extraction of Aerva sanguinolenta plants, the best solvent to dissolve the plants, the extract's color, the paper type which would be used, and prediction on pH route change, and colors that formed from the indicator papers were formulated.
Natural dyes found in plants are widely used as natural indicators, for example, curcumin as an alternative substitute for the phenolphthalein and methyl orange indicators (Sundari, 2016). Aerva sanguinolenta can be used as an alternative indicator because in the plant there is one natural water-soluble dye called anthocyanin. Anthocyanins were found in many flowers and fruits such as roses, hibiscus, chrysanthemums, apples, cherries, grapes, strawberries, also found in the mangosteen, red spinach, dragon fruit, and sweet potato tubers (Subodro, 2012).

Figure 2. The Predict Phase
The observe phase of the worksheet can be seen in Figure 3.

The Development of Worksheet in the Chemistry Experiment Learning of Creating Natural Indicator Papers
In the observe phase, an experiment was conducted and observed. Any occurring phenomenon was recorded and compared to the hypotheses/assumptions. In this phase, instruction was given, consisting of writing the title, objectives, and procedure of the experiment, tools, and materials based on the procedure, and conducting an experiment in which several variables are observed, such as the comparison of the creation of indicator papers using decoction and maceration methods, the comparison between methanol, ethanol and water solvents, the comparison between Whatman TM no.40 filter papers, HVS papers, and coarse filter papers, and pH scale testing on the newly created paper indicators.
The observation of the pH scale shows that there is a change in color in the pH range 11-12 where the color changes from red-purple to yellow. This is because the stability of anthocyanin in the Aerva sanguinolenta was influenced by the pH of the solution when in an acidic atmosphere it turns red-purple while in an alkaline atmosphere it turns yellow. Anthocyanins when in the solution were in five forms of equilibrium depending on the pH conditions. At a very acidic pH of 1-2, anthocyanin was in the predominant form of the flavillium cation. In this form, anthocyanin was in the most stable and most colorful condition, which is red. When the pH rises above 4 it turns yellow anthocyanin compounds (chalcone form), blue compounds (quinoid form), or colorless compounds (carbinol bases) (Mahmudatussa'adah et al., 2014).
The explain phase of the worksheet can be seen in Figure 4. In the explain phase, the compatibility between hypotheses created in the predict phase and the observation results was explained. In this phase, students were asked, based on their findings, to explain the extraction process and method from Aerva sanguinolenta plants, the characteristics of the extract, types of solvent and indicator paper used, the absorption of the extract on the indicator papers and to conclude the creation of the indicator papers from the plants. The results of the comparison of the types of extraction methods and types of solvents show that ethanol solvents with the decoction method were better than the maceration method, which is 79.2 mg / L. Anthocyanins can be degraded due to several factors, one of which is temperature or heating. In general anthocyanin degradation can occur due to the presence of the enzyme polyphenol oxidase. The polyphenol oxidase enzyme plays a role in the enzymatic browning reaction of phenolic compounds. This enzyme can be inactivated by moderate heating (<50 ⁰C). This can be the reason why the decoction or heating method shows a better method by producing higher levels of anthocyanin than using the maceration method. We can also conclude that the most optimum type of paper used as indicator paper is rough filter paper. This is due to coarse filter paper containing cellulose with pores that are medium (medium), so the solution/extract that is absorbed by the paper has the ability of capillarity to flow the solution without damaging the color of the paper.
The worksheet then tested regarding its product feasibility by three validators who were Chemistry Education Lecturers. The The Development of Worksheet in the Chemistry Experiment Learning of Creating Natural Indicator Papers recapitulation of the feasibility test scores from the three validators is presented in Table 1. After the feasibility test results were considered valid, the percentages of the values are created and presented in Table 2. The first validator gave 85% because some errors in writing were found. After the errors were corrected, the draft was given to the second and third validators for more checking and feedback. Then both validators gave 95%. Therefore, the average value percentage gained was 92%.
The worksheet was tested regarding its readability by students, the content assessment is carried out in the form of a questionnaire. The highest value was generated from all students is the procedure for making indicator paper from Aerva sanguinolenta plant and has a compatibility with acid-base material with a percentage of 100%. This indicates that the questions in the worksheet are easy to understand. The lowest value obtained from the student questionnaire is in the aspect of understanding instruction at the explain stage with a percentage of 89%. This indicates that the instructions in the explain phase given on the worksheet are not all understood and understood by students, so there is a need for direction on these instructions. The results of this readability trial test obtainid in an average percentage of 93% and were categorized as very valid so that the worksheet was suitable for use.

CONCLUSION
The POE based worksheet was created based on the define, design and develop method. In the define phase, a literature review was performed to formulate the steps of POE based learning and the procedure of creating indicator papers from Aerva sanguinolenta