Analisis Kadar Patchouli Alcohol Menggunakan Gas Chromatography– Mass Spectrometry (GC – MS) pada Pemurnian Minyak Nilam (Pogostemon cablin B.) Aceh Tamiang dengan Nanomontmorillonite
DOI:
https://doi.org/10.15575/ak.v8i2.14305Keywords:
Minyak Nilam, Kadar PA, Nano-MMT.Abstract
Tanaman nilam (Pogostemon cablin Benth.) merupakan salah satu tanaman penghasil minyak atsiri atau yang lebih dikenal dengan nama Patchouli Alcohol (PA). PA merupakan senyawa yang terbesar di dalam minyak nilam sebagai penentu mutu minyak nilam, kadar PA dalam minyak nilam menurut SNI 06-2385-2006 yaitu minimal 30%. Sampel minyak nilam yang digunakan adalah minyak nilam yang berasal dari Aceh Tamiang. Tujuan penelitian ini dilakukan untuk mengetahui kadar PA sebelum dan sesudah adsorbsi menggunakan Nanomontmorillonite (Nano-MMT) sebagai adsorben dengan menggunakan metode kualitatif dengan uji warna dan metode kuantitatif dengan analisis Gas Cromatography Mass Spectrometry (GC-MS) untuk menentukan kadar PA, mengingat Nano-MMT adalah jenis tanah liat (clay) yang dapat digunakan sebagai adsorben yang mengadsorpsi kontaminan metalik dengan baik dikarenakan Nano-MMT mempunyai muatan negatif yang dapat mengikat spesies yang bermuatan positif kontaminan metalik seperti logam berat. Berdasarkan hasil analisis diketahui bahwa kadar PA sebelum diadsorpsi 7,74% b/v, dan kadar PA setelah diadsorpsi berkisar antara 4,47%-7,86% b/v, kadar tersebut belum sesuai dengan SNI. Hal ini disebabkan karena banyak hal diantaranya terdapat komponen pengotor berupa kontaminan metalik seperti logam, terjadinya oksidasi, tercampurnya minyak nilam dengan bahan lain, pencemaran wadah penyulingan minyak, dan waktu penyimpanan yang relatif lama.
References
N.F.N. Wati, "Peningkatan Kualitas Minyak Nilam Melalui Proses Adsorpsi Menggunakan Adsorben y- Alumina dengan system Flow", Indonesian Journal Of Chemical Reaserch, vol. 1, no. 2, pp. 84-95, 2014.
O. Sariadi, "Pemurnian Minyak Nilam Dengan Proses Adsorpsi Menggunakan Bentonit", Jurnal Teknologi, vol. 12, no. 2, pp. 100-104, 2012.
Dinas Perkebunan Provinsi Jawa Timur, Budidaya Tanaman Nilam. Dinas Perkebunan Provinsi Jawa Timur Pengembangan Sarana Dan Prasarana Pembangunan Perkebunan, Jawa Timur, 2013.
A. Idris, M.R. Jura, and I. Said, "Analisis Kualitas Minyak Nilam (Pogestemon cablin Benth) Produksi Kabupaten Boul", Jurnal Akademika Kimia, vol 3, no. 2, pp. 79-85, 2014.
S. Shinta, "Potensi Minyak Atsiri Daun Nilam (Pogostemon cablin Benth), Daun Babadotan (Ageratum conyzoides L), Bunga Kenanga (Cananga odorata hook F & Thoms), dan Daun Rosemarry (Rosmarinus officinalis L) Sebagai Repelan Terhadap Nyamuk Aedes Aegypti L.", Media Litbang Kesehatan, vol. 22, no. 2, pp. 61-69, 2012.
Y. Aisyah, P. Hastuti, H. Sastrohamidjojo, and C. Hidayat, "Teknologi Pervaporasi Peningkatan Kadar Patchouli Alcohol Minyak Nilam Menggunakan Membran Selulosa Asetat", argiTECH, vol. 32, no. 2, pp. 207-213, 2012.
M.D. Supardan, A. Fatanen, and C. Erika, "Lemongras Oil Adsorption Using Bentonit", Jurnal Hasil Penelitian Industri, vol. 28, no. 2, pp. 88-94, 2015.
T.T. Tee, L.T. Sin, R. Gobinath, S.T. Bee, D. Hui, A.R. Rahmat, and Q. Fang, "Investigation of Nano-Size montmorillonit on Enhancing Polyvinyl Alcohol- Starch Blends Prepared via Solution Cast Approach", Composite part B: Engineering, vol. 47, pp. 238-247, 2013.
F. Susanti, T. Harmawan, and P. Wahyuningsih, "Pengaruh Interkalasi Mikro Montmorillonit Dengan Mikro Kitosan Sebagai Adsorben Untuk Meningkatkan Mutu Minyak Nilam", Jurnal Kimia dan Kemasan, vol. 43, no. 2, pp. 133-142, 2021.
A. Allwar, F. Is, N. Fitri, and D. Rubiyanto, "Improvement of The Product and Quality of Pogostemon cablin Benth", EKSAKTA: Journal of Sciences and Data Analysis, vol. 14, no. 1, pp. 34-41, 2014.
I.S. Hardyanti, D. Septyaningsih, I. Nuraini, and A. P. Wibowo, "Analisis Kadar Patchouli Alcohol Menggunakan Gas Chromatography pada Pemurnian Minyak Nilam Menggunakan Adsorben Zeolit", Jurnal Rekayasa Teknologi Industri dan Informasi, vol. 2, no. 1, pp. 392-395, 2016.
S. Ningsih, P. Wahyuningsih, and T. Harmawan, "Effectiveness Bleaching of Waste Cooking Oil Cleaning Using Nano-Montmorillonite Adsorbent", Elkawnie: Journal of Islamic Science and Technology, vol. 7, no. 2, 2021.
T. Harmawan, Y. Amri, and T.A. Fadly, "Isolation and Characterization Montmorillonite Nanoparticles of Aceh Tamiang Bentonite as Pathouli oil (Pogostemon cablin) Bleahing", Oriental Journal of Chemistry, vol. 35, no. 5, pp. 1535-1538, 2019.
P. Wahyuningsih, T. Harmawan, R., Fajri, and R.A. Putra, "Synthesis of Biodiesel from Waste Cooking Oil Using the Sulfated Montmorillonite", In 2nd International Conference on Science, Technology, and Modern Society (ICSTMS 2020), Atlantis Press, pp. 28-31, 2021.
P. Wahyuningsih and T. Harmawan, "Synthesis and Characteritation of Acid-Activated Bentonite from Aceh Tamiang," In IOP Conference Series: Materials Siene and Engineering, vol. 725, no. 1, pp. 012050, 2020.
L. Zhirong, M.A. Uddin, and S. Zhanxue, "FT-IR and XRD Analysis of Natural Na-Bentonite and Cu (II)-loaded-Na-Bentonite", Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, vol. 79, no. 5, pp. 1013– 1016, 2011.
J. da Silva Favero, V. dos Santos, V. Weiss-Angeli, L.B. Gomes, D.G. Veras, N. Dani, and C.P. Bergmann, "Evaluation and characterization of Melo Bentonite clay for cosmetic applications", Applied Clay Science, vol. 175, pp. 40-46, 2019.
A. Kumar and P. Lingfa, "Sodium bentonite and kaolin clays: Comparative study on their FT-IR, XRF, and XRD", Materials Today: Proceedings, vol. 22, pp. 737-742, 2020.
D.O.B. Apriandanu, S. Wahyuni, S. Hadisaputro, and H. Harjono, "Sintesis Nanopartikel Perak Menggunakan Metode Poliol Dengan Agen Stabilisator Polivinilalkohol (PVA)", Indonesian Journal of Mathematics and natural Sciences, vol. 36, no. 2, pp. 157-168, 2013.
P. Morters and Y. Peres, Brownian Motion. Cambridge University Press. vol. 30, 2010.
A. Fisli and S. Yusuf, "Sintesis Nanokomposit Magnetik Berbasis Bahan Alam Untuk Adsorben Thorium", Jurnal Sains Materi Indonesia, vol. 11, no. 2, pp. 93-98, 2010.
S. Zaimah, "Pengujian Kualitas dan Komposisi Kimia Minyak Nilam (Pogostemon cablin Benth)", Indonesian Journal of Chemical Research, vol. 2, no. 1, pp. 1-9, 2014.
M. Pentrák, V. Hronský, H. Pálková, P. UhlÃk, P. Komadel, and J. Madejová, "Alteration of fine fraction of bentonite from Kopernica (Slovakia) under acid treatment: a combined XRD, FTIR, MAS NMR and AES study", Applied Clay Science, vol. 163, pp. 204-213, 2018.
T. Harmawan, W. Ani, P. Andani, and T. A. Fadlly, "Production of Biodiesel Through Transesterification of Crude Palm Oil (CPO) Using Montmorillonite Nanoparticles (Nano-MMT) as Heterogeneous Solid Catalyst", In 2nd International Conference on Science, Technology, and Modern Society (ICSTMS 2020), Atlantis Press, pp. 69-72, 2021.
Downloads
Published
Issue
Section
License
Authors who publish with this journal agree to the following terms:
- Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution 4.0 International License that allows others to share the work with an acknowledgment of the work's authorship and initial publication in this journal.
- Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgment of its initial publication in this journal.
- Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (See The Effect of Open Access).
