Sintesis dan Karakterisasi Surfaktan Lignosulfonat dari Lignin Alkali Standar dan Lignosulfonat Teraminasi dari Lignosulfonat Standar

Authors

  • Nila Tanyela Berghuis Program Studi Kimia Fakultas Sains dan Komputer Universitas Pertamina, Indonesia https://orcid.org/0000-0002-9641-4210
  • Anggun Kirana Devi Shaenazha Putri Program Studi Kimia Fakultas Sains dan Komputer Universitas Pertamina, Indonesia
  • Eng Paramita Jaya Ratri Program Studi Kimia Fakultas Sains dan Komputer Universitas Pertamina, Indonesia
  • Syiffa Assatyas Program Studi Kimia Fakultas Sains dan Komputer Universitas Pertamina, Indonesia
  • Septhian Marno Program Studi Kimia Fakultas Sains dan Komputer Universitas Pertamina, Indonesia
  • Nelliza Putri Program Studi Kimia Fakultas Sains dan Komputer Universitas Pertamina, Indonesia
  • Eng Bayu Prabowo Program Studi Kimia Fakultas Sains dan Komputer Universitas Pertamina, Indonesia

DOI:

https://doi.org/10.15575/ak.v9i1.17550

Keywords:

Lignin alkali, lignosulfonat, lignosulfonat teraminasi, surfaktan, tegangan antarmuka.

Abstract

Ketersediaan lignin yang melimpah dan efisiensi biaya, lignosulfonat dapat digunakan sebagai stabilisasi surfaktan. Penelitian ini melakukan sintesis surfaktan lignosulfonat dan lignosulfonat teraminasi dengan tujuan untuk menghasilkan gugus sulfonat pada lignin alkali standar dan gugus amina pada lignosulfonat standar serta mengetahui nilai tegangan antarmuka lignosulfonat teraminasi hasil sintesis. Metode yang digunakan adalah sulfonasi lignin alkali standar  menggunakan reaksi substitusi elektrofilik dan aminasi lignosulfonat standar menggunakan reaksi Mannich. Lignosulfonat hasil sintesis akan dikarakterisasi menggunakan FTIR (Fourier Transform Infrared) dan lignosulfonat teraminasi hasil sintesis akan dikarakterisasi menggunakan FTIR dan IFT (Interfacial Tension) tensiometer. Karakterisasi lignosulfonat hasil sintesis menggunakan FTIR menunjukkan adanya perbedaan kemunculan vibrasi ikatan dengan lignin alkali standar. Perbedaan dapat terlihat dengan adanya vibrasi ikatan S=O sulfat pada bilangan gelombang 1420,78 cm-1 dan C-S-O pada bilangan gelombang 623,37 cm-1 pada lignosulfonat hasil sintesis. Karakterisasi FTIR lignosulfonat teraminasi hasil sintesis menunjukkan adanya vibrasi ikatan N-H pada bilangan gelombang 3258,62 cm-1 dan vibrasi ikatan C-N pada bilangan gelombang 1214,45 cm-1. Kedua vibrasi ikatan tersebut tidak dapat ditemukan pada hasil analisis FTIR lignosulfonat standar. Hasil pengukuran IFT menunjukkan nilai tegangan antarmuka lignosulfonat teraminasi hasil sintesis sebesar 2,124 mN/M. Nilai tegangan antarmuka lignosulfonat teraminasi hasil sintesis yang lebih rendah dari lignin alkali hasil isolasi tandan kosong kelapa sawit dan lignosulfonat standar menunjukkan bahwa penggunaan amina primer berupa etilendiamin dapat mempengaruhi lipofilisitas lignosulfonat teraminasi sebagai surfaktan.

References

F. Dalena and A. Basile, Eds., Bioenergy systems for the future prospects for biofuels and biohydrogen. India: Elsevier Ltd., 2017.

A.J.M. Mackus, A. Bol, and W.M.M. Kessels, “The use of atomic layer deposition in advanced nanopatterningâ€, Nanoscale, vol. 6, no. 19, pp. 10941–10960, 2014.

S. Priyanto, A. Nugroho, H.A. Aji, and B. Pramudono, "Preliminary study of development surfactant sodium ligno sulfonate (SLS) from waste biomass in the application of enhanced oil recovery (EOR) yield increase in production for crude oil Indonesia", Advanced Science Letters, vol. 23, no. 6, pp. 5803-5805, 2017.

J. Rakowska, K. Radwan, B. Porycka, and K. Prochaska, "Experimental study on surface activity of surfactants on their ability to cleaning oil contaminations", Journal of cleaner production, vol. 144, pp. 437-447, 2017.

J.Y. Zhang, L. Ge, W. Qin, Huang, and Z. Li, “Synthesis of a lignin-based surfactant through amination, sulfonation, and acylation,†Journal Of Dispersion Science and Technology, vol. 39, no. 8, pp. 1140–1143, 2018.

A. Rabiu, S. Elias, and O. Oyekola, "Oleochemicals from palm oil for the petroleum industry", Palm Oil, pp. 91, 2018.

M. Patel, “Surfactants based on renewable raw materials carbon dioxide reduction potential and policies and measures for the european union", Journal of Industrial Ecology, vol. 7, no. 3, pp. 47–62, 2004.

D.S. Bajwa, G. Pourhashem, A.H. Ullah, and S.G. Bajwa, “A concise review of current lignin production, applications, products and their environmental impactâ€, Industrial Crops and Products., vol. 139, no. 2, pp. 111526, 2019.

F. Rosillo-Calle, P. de Groot, S.L. Hemstock, and J. Woods, "Non-Woody Biomass and Secondary Fuels", The Biomass Assessment Handbook, Taylor and Francis, vol. 4, pp. 110, 2012.

N. Mandlekar, A. Cayla, F. Rault, S. Giraud, F. Salaün, et al., "An overview on the use of lignin and its derivatives in fire retardant polymer systems", Lignin-Trends and Applications, vol. 9, pp. 207-231, 2018.

M.M. Heravi, Z. Kheilkordi, V. Zadsirjan, M. Heydari, and M. Malmir, “Buchwald-Hartwig reaction: An overview,†Journal Of Organometallic Chemistry, vol. 861, pp. 17–104, 2018.

C. Xu, and F. Ferdosian, "Conversion of lignin into bio-based chemicals and materials", Germany: Springer-Verlag, pp. 91-109, 2017.

Y. Ge, D. Xiao, Z. Li, and X. Cui, "Dithiocarbamate functionalized lignin for efficient removal of metallic ions and the usage of the metal-loaded bio-sorbents as potential free radical scavengers", Journal of Materials Chemistry A, vol. 2, no. 7, pp.2136-2145, 2014.

Z. Li, Y. Kong, and Y. Ge, "Synthesis of porous lignin xanthate resin for Pb2+ removal from aqueous solution", Chemical Engineering Journal, vol. 270, pp.229-234, 2015.

D.M.J. Kai, P.L. Tan, Y. K. Chee, Y.L. Chua, Yap, and X.J. Loh, “Towards lignin-based functional materials in a sustainable world,†Green Chemistry., vol. 18, no. 5, pp. 1175–1200, 2016.

G. Shabir, I. Shafique, and A. Saeed, "Ultrasound Assisted Synthesis of 5â€7 Membered Heterocyclic Rings in Organic Molecules", Journal of Heterocyclic Chemistry. 2022.

D. Xueyu, J. Li, and M.E. Lindström, “Modification of industrial softwood kraft lignin using Mannich reaction with and without phenolation pretreatmentâ€, Industrial Crops and Products., vol. 52, pp. 729–735, 2014.

N.T. Giang, “A new synthesis process of lignosulfonate using lignin recovered from black liquor of pulp and paper millsâ€, Vietnam Journal Of Science and Technology, vol. 54, no. 4B, p. 1, 2018.

P.Q. Li, J. Lu, R.F. Yang, and Y.J. Liu, "Comparison of structures and properties of lignosulfonate in different pulping waste liquors", In Advanced Materials and Energy Sustainability: Proceedings of the 2016 International Conference on Advanced Materials and Energy Sustainability (AMES2016), pp. 273-278, 2017.

Y.Z. Jiao, W. Xu, Qiao, and Z. Li, “Research Interfacial properties of the novel lignosulfonatesâ€, Energy Sources, Part A Recovery Utilization Environmental Effects., vol. 29, no. 15, pp. 1425–1432, 2007.

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Published

2022-07-01

Issue

Vol. 9 No. 1 (2022): al Kimiya: Jurnal Ilmu Kimia dan Terapan

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